1579249-10-7Relevant academic research and scientific papers
Purification-free, small-scale synthesis of isothiocyanates by reagentless fragmentation of polymer-supported 1,4,2-oxathiazoles
Burkett, Brendan A.,Fu, Pincheng,Hewitt, Russell J.,Ng, Su Ling,Toh, Joel D. W.
, p. 1053 - 1058 (2014/03/21)
The synthesis of isothiocyanates (ITCs) by employing polymer-supported 1,4,2-oxathiazoles is described. The ITCs are obtained in moderate yields and high purity through a reagentless, thermal fragmentation of polymer-supported 1,4,2-oxathiazoles that are obtained by trapping nitrile oxides with polymer-supported thiocarbonates. A purification-free, small-scale synthesis for isothiocyanates (ITCs) is reported that proceeds through a catch-and-release system. This is a convenient method to produce small quantities of ITCs in high purity for screening purposes. Copyright
Purification-Free, Small-Scale Synthesis of Isothiocyanates by Reagentless Fragmentation of Polymer-Supported 1,4,2-Oxathiazoles
Burkett, Brendan A.,Fu, Pincheng,Hewitt, Russell J.,Ng, Su Ling,Toh, Joel D. W.
, p. 1053 - 1058 (2015/10/05)
The synthesis of isothiocyanates (ITCs) by employing polymer-supported 1,4,2-oxathiazoles is described. The ITCs are obtained in moderate yields and high purity through a reagentless, thermal fragmentation of polymer-supported 1,4,2-oxathiazoles that are obtained by trapping nitrile oxides with polymer-supported thiocarbonates. A purification-free, small-scale synthesis for isothiocyanates (ITCs) is reported that proceeds through a catch-and-release system. This is a convenient method to produce small quantities of ITCs in high purity for screening purposes.
