1579259-79-2Relevant academic research and scientific papers
κ2-Coordination of 18-crown-6 to Ce(iii) cations: Solution dynamics and reactivity
Yin, Haolin,Robinson, Jerome R.,Carroll, Patrick J.,Walsh, Patrick J.,Schelter, Eric J.
, p. 3470 - 3472 (2014)
The coordination of 18-crown-6 to Ce[N(SiMe3)Ph F]3 (PhF = pentafluorophenyl) results in a κ2-18-crown-6 complex, a unique coordination mode for an f-block cation. The κ2-18-crown-6 complex showed exchange with free 18-crown-6 in solution and facile rearrangement of the crown ligand into a κ6-18-crown-6 cerium complex.
