157952-83-5

Basic information

• Product Name: 2-iodo-6,6-dimethylcyclohex-2-en-1-one
• Synonyms: 2-iodo-6,6-dimethylcyclohex-2-en-1-one
• CAS NO: 157952-83-5
• Molecular Weight: 250.079
• Mol File: 157952-83-5.mol

Chemical Properties

• CAS DataBase Reference: 2-iodo-6,6-dimethylcyclohex-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2-iodo-6,6-dimethylcyclohex-2-en-1-one(157952-83-5)
• EPA Substance Registry System: 2-iodo-6,6-dimethylcyclohex-2-en-1-one(157952-83-5)

Safety Data

• Hazardous Substances Data: 157952-83-5(Hazardous Substances Data)

Upstream product

• 583-60-8 2-Methylcyclohexanone 
• 6553-64-6 6,6-Dimethyl-2-cyclohexen-1-one 

Downstream Products

• 181276-76-6 6,6-Dimethyl-2-trimethylsilanylethynyl-cyclohex-2-enone 
• 157952-81-3 6,6-Dimethyl-2-(3,3-dimethylbutynyl)-2-cyclohexen-1-one 

Relevant articles and documents

Furans from novel [3+2] photocycloaddition of alkenes to 2-(1-alkynyl)cyclohexenones

Photocycloaddition of 2-alkynyl-substituted cyclohexenones 8c-11c with isobutylene (2) and tetramethylethylene (3a) leads to tricyclic furans 15a-18a and 15b-17b, respectively, in gas chromatographic yields of ~90%. A suggested mechanism for this novel pr

11-Step Total Synthesis of (-)-Maoecrystal v

An expedient, practical, and enantioselective route to the highly congested ent-kaurane diterpene maoecrystal V is presented. This route, which has been several years in the making, is loosely modeled after a key pinacol shift in the proposed biosynthesis. Only 11 steps, many of which are strategic in that they build key skeletal bonds and incorporate critical functionalities, are required to access (-)-maoecrystal V. Several unique and unexpected maneuvers are featured in this potentially scalable pathway. Reevaluation of the biological activity calls into question the initial exuberance surrounding this natural product.