157954-28-4

Basic information

• Product Name: 4,4-Bis(phenylthio)-1-(m-bromophenyl)-3-butenol
• CAS NO: 157954-28-4
• Molecular Weight: 443.428
• Mol File: 157954-28-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4,4-Bis(phenylthio)-1-(m-bromophenyl)-3-butenol(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4-Bis(phenylthio)-1-(m-bromophenyl)-3-butenol(157954-28-4)
• EPA Substance Registry System: 4,4-Bis(phenylthio)-1-(m-bromophenyl)-3-butenol(157954-28-4)

Safety Data

• Hazardous Substances Data: 157954-28-4(Hazardous Substances Data)

Upstream product

• 3132-99-8 m-bromobenzoic aldehyde 
• 71341-78-1 methylketene diphenyldithioacetal 

Downstream Products

• 157955-10-7 4,4-Bis(phenylthio)-1-(m-bromophenyl)-3-butenyl acetate 

Relevant articles and documents

Resolution of homoallylic alcohols containing dithioketene acetal functionalities. Synthesis of optically active γ-lactones by a combination of chemical and enzymatic methods

Racemic homoallylic alcohols 1-3 containing dithioketeneacetal functionalities were prepared by addition of aldehydes to the allylic anions of ketene dithioacetals or 2-alkenyl-1,3-dithiane in a regio- and stereoselective manner. Lipase-catalyzed hydrolyses of the corresponding acetates 7-9 afforded optically active alcohols 1-3, which were treated with mercuric chloride to give γ-lactones such as natural hop lactone, whiskey lactone, and cognac lactone.