158014-32-5Relevant academic research and scientific papers
SO-Photoextrusion of 7-Thiabicyclohept-2-ene 7-Oxides
Thiemann, Carolin,Thiemann, Thies,Li, YuanQiang,Sawada, Tsuyoshi,Nagano, Yoshiaki,Tashiro, Masashi
, p. 1886 - 1893 (1994)
The photoextrusion of the SO-bridge of 7-thiabicyclohept-2-ene 7-oxides is discussed.An analysis of all the major by-products in the exemplary case of the photo reaction of 3a is given.The existence of intermediate dienes 4 has been established.Dat
CYCLOADDITIONS DES ARSOLES A HAUTE TEMPERATURE
Sennyey, Gerard,Mathey, Francois
, p. 4713 - 4716 (2007/10/02)
At room temperature 1-phenyl-2,5-dimethylarsole 1 gives cycloadditions with dienophiles whereas at 160 deg C it yields arsenic atoms which react with tolane to give the 1,4-diarsabicyclooctatriene 8 ; 1,2,5-triphenylarsole 2 is less reactive a
