1580457-78-8

Basic information

• Product Name: (S)-5-methyl-2-(6-methylhept-5-en-2-yl)benzaldehyde
• Synonyms: (S)-5-methyl-2-(6-methylhept-5-en-2-yl)benzaldehyde
• CAS NO: 1580457-78-8
• Molecular Weight: 230.35
• Mol File: 1580457-78-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-5-methyl-2-(6-methylhept-5-en-2-yl)benzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-5-methyl-2-(6-methylhept-5-en-2-yl)benzaldehyde(1580457-78-8)
• EPA Substance Registry System: (S)-5-methyl-2-(6-methylhept-5-en-2-yl)benzaldehyde(1580457-78-8)

Safety Data

• Hazardous Substances Data: 1580457-78-8(Hazardous Substances Data)

Upstream product

• 1580457-77-7 (S)-(5-methyl-2-(6-methylhept-5-en-2-yl)phenyl)methanol 
• 1580457-76-6 (S)-5-methyl-2-(6-methylhept-5-en-2-yl)benzoic acid 
• 1580457-74-4 5-methyl-2-(6-methylhepta-1,5-dien-2-yl)benzoic acid 
• 1580457-73-3 C₁₇H₂₂O₂ 
• 916260-44-1 2-bromo-6-methyl-1,5-heptadiene 
• 1256355-43-7 2-methoxycarbonyl-4-methylphenylboronic acid 

Downstream Products

• 109028-15-1 (S)-2-(6-hydroxy-6-methylheptan-2-yl)-5-methylphenol 

Relevant articles and documents

Carboxy-directed asymmetric hydrogenation of α-alkyl-α-aryl terminal olefins: Highly enantioselective and chemoselective access to a chiral benzylmethyl center

A carboxy-directed asymmetric hydrogenation of α-alkyl-α-aryl terminal olefins was developed by using a chiral spiro iridium catalyst, providing a highly efficient approach to the compounds with a chiral benzylmethyl center. The carboxy-directed hydrogenation prohibited the isomerization of the terminal olefins, and realized the chemoselective hydrogenation of various dienes. The concise enantioselective syntheses of (S)-curcudiol and (S)-curcumene were achieved by using this catalytic asymmetric hydrogenation as a key step.