1581756-72-0Relevant academic research and scientific papers
Nitroarenes as the Nitrogen Source in Intermolecular Palladium-Catalyzed Aryl C–H Bond Aminocarbonylation Reactions
Zhou, Fei,Wang, Duo-Sheng,Guan, Xinyu,Driver, Tom G.
, p. 4530 - 4534 (2017)
A three-component palladium-catalyzed aminocarbonylation of aryl and heteroaryl sp2 C?H bonds using nitroarenes as the nitrogen source was achieved using Mo(CO)6 as the reductant and origin of the CO. This intermolecular C?H bond functionalization does not requires any exogenous ligand to be added, and our mechanism experiments indicate that the palladacycle catalyst serves two roles in the aminocarbonylation reaction: reduce the nitroarene to a nitrosoarene and activate the sp2 C?H bond.
