1581756-85-5Relevant academic research and scientific papers
N-Methoxyamide: An Alternative Amidation Reagent in the Rhodium(III)-Catalyzed C-H Activation
Zhou, Chao,Zhao, Junqi,Guo, Weicong,Jiang, Jijun,Wang, Jun
supporting information, p. 9315 - 9319 (2019/11/28)
In the field of transition-metal-catalyzed C-H activation, N-methoxyamides are widely used as C-H activation substrate. Unexpectedly, in this work N-methoxyamides were found to work as efficient amidation reagents in the rhodium(III)-catalyzed C-H activation with boric acid as a cocatalyst. This reaction features broad substrate scope and good yields.
Orthogonal reactivity of acyl azides in C-H activation: Dichotomy between C-C and C-N amidations based on catalyst systems
Shin, Kwangmin,Ryu, Jaeyune,Chang, Sukbok
supporting information, p. 2022 - 2025 (2014/05/06)
The dual reactivity of acyl azides was utilized successfully in C-H activation by the choice of catalyst systems: while selective C-C amidation was achieved under thermal Rh catalysis, a Ru catalyst was found to mediate direct C-N amidation also highly se
