158194-79-7

Basic information

• Product Name: p-Methoxyphenyl 2,3-di-O-p-methylbenzoyl-β-D-glucopyranoside
• Synonyms: p-Methoxyphenyl 2,3-di-O-p-methylbenzoyl-β-D-glucopyranoside
• CAS NO: 158194-79-7
• Molecular Weight: 522.552
• Mol File: 158194-79-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: p-Methoxyphenyl 2,3-di-O-p-methylbenzoyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: p-Methoxyphenyl 2,3-di-O-p-methylbenzoyl-β-D-glucopyranoside(158194-79-7)
• EPA Substance Registry System: p-Methoxyphenyl 2,3-di-O-p-methylbenzoyl-β-D-glucopyranoside(158194-79-7)

Safety Data

• Hazardous Substances Data: 158194-79-7(Hazardous Substances Data)

Upstream product

• 2872-65-3 p-methoxyphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 
• 150-76-5 4-methoxy-phenol 
• 604-69-3 β-D-glucose pentaacetate 
• 3150-20-7 4-methoxyphenyl β-D-glucopyranoside 
• 180274-49-1 p-Methoxyphenyl 4,6-O-isopropylidene-β-D-glucopyranoside 
• 874-60-2 4-methyl-benzoyl chloride 
• 158194-78-6 4-methoxyphenyl 4,6-O-benzylidene-2,3-di-O-p-toluoyl-β-D-glucopyranoside 

Downstream Products

• 144367-32-8 4-methoxyphenyl 6-O-levulinoyl-2,3-di-O-p-toluoyl-β-D-glucopyranoside 
• 144367-33-9 4-methoxyphenyl 6-O-levulinoyl-2,3,4-tri-O-p-toluoyl-β-D-glucopyranoside 
• 144367-34-0 4-methoxyphenyl 4-O-allyloxycarbonyl-6-O-levulinoyl-2,3-di-O-p-toluoyl-β-D-glucopyranoside 
• 180274-56-0 p-Methoxyphenyl O-(3,4,6-tri-O-acetyl-2-azido-2-deoxy-β-D-glucopyranosyl)-(1->4)-6-O-tert-butyldiphenylsilyl-2,3-di-O-p-methylbenzoyl-β-D-glucopyranoside 
• 180274-60-6 (2S,3S,4S,5R,6R)-3-((2R,3R,4R,5S,6R)-4,5-Diacetoxy-6-acetoxymethyl-3-azido-tetrahydro-pyran-2-yloxy)-4,5-bis-(4-methyl-benzoyloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 180274-58-2 (2S,3S,4S,5R,6S)-3-((2R,3R,4R,5S,6R)-4,5-Diacetoxy-6-acetoxymethyl-3-azido-tetrahydro-pyran-2-yloxy)-6-(4-methoxy-phenoxy)-4,5-bis-(4-methyl-benzoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 180274-57-1 p-Methoxyphenyl O-(3,4,6-tri-O-acetyl-2-azido-2-deoxy-β-D-glucopyranosyl)-(1->4)-2,3-di-O-p-methylbenzoyl-β-D-glucopyranoside 
• 180274-59-3 (2S,3S,4S,5R,6S)-3-((2R,3R,4R,5S,6R)-4,5-Diacetoxy-6-acetoxymethyl-3-azido-tetrahydro-pyran-2-yloxy)-6-hydroxy-4,5-bis-(4-methyl-benzoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 180274-50-4 p-Methoxyphenyl 6-O-tert-butyldiphenylsilyl-2,3-di-O-p-methylbenzoyl-β-D-glucopyranoside 

Relevant articles and documents

Synthetic studies of glycosyl serines in the carbohydrate-protein region of protoglycans

A series of glycosyl serines 1-6 which are located in the carbohydrate-protein linkage region of proteoglycans, including the chondroitin penta- and heptasaccharides GalNAcα(1-4)R (3), GalNAcβ(1-4)R (4) and GalNAcβ(1-4)GlcAβ(1-3)GalNAc(1-4)R (6) as well as the heparin pentasaccharide GlcNAcα(1-4)R (5) [R = GlcAβ(1-3)Galβ(1-3)Galβ(1-4)Xylβ-Ser] were systematically synthesized as follows. Trisaccharide acceptor 27 having a Gal(1-3)Galβ(1-4)Xyl sequence was glycosylated with di- and tetrasaccharide donors 16α, 16β, 22, and 26, which correspond to the non-reducing end sequences of 3-6, regio- and stereoselectively to afford penta- and heptasaccharides 30, 34, 36, and 39, respectively. After the conversion into the respective penta- and heptaosylimidates 42c-f as well as tri- and tetraosylimidates 42a and b, they were coupled with serine derivative 43 to give tri-, tetra-, penta-, and heptaosyl serines 44a-f. All the glycosyl serines were deprotected to 1-6. VCH Verlagsgesellschaft mbH, 1996.