1582289-15-3

Basic information

• Product Name: p-methoxyphenyl O-{6-O-(TEMPO-4-carbonyl)}-β-D-glucoside
• Synonyms: p-methoxyphenyl O-{6-O-(TEMPO-4-carbonyl)}-β-D-glucoside
• CAS NO: 1582289-15-3
• Molecular Weight: 468.524
• Mol File: 1582289-15-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: p-methoxyphenyl O-{6-O-(TEMPO-4-carbonyl)}-β-D-glucoside(CAS DataBase Reference)
• NIST Chemistry Reference: p-methoxyphenyl O-{6-O-(TEMPO-4-carbonyl)}-β-D-glucoside(1582289-15-3)
• EPA Substance Registry System: p-methoxyphenyl O-{6-O-(TEMPO-4-carbonyl)}-β-D-glucoside(1582289-15-3)

Safety Data

• Hazardous Substances Data: 1582289-15-3(Hazardous Substances Data)

Upstream product

• 37149-18-1 1-oxyl-4-carboxyl-2,2,6,6-tetramethylpiperidine 
• 3150-20-7 4-methoxyphenyl β-D-glucopyranoside 

Relevant articles and documents

Evaluation of glucose-linked nitroxide radicals for use as an in vivo spin-label probe

In vivo incorporation and reduction abilities of 4-carboxy-2,2,6,6- tetramethylpiperidine-1-oxyl (4-carboxy-TEMPO) (1), 3-carboxy-2,2,5,5- tetramethylpyrroline-1-oxyl (3-carboxy-dehydro-PROXYL, 3-carboxy-DPRO) (2), 4-hydroxy-TEMPO and 3-hydroxymethyl-DPRO O-β-D-glucosides (3 and 5), and newly designed forms of 6-O-(TEMPO-4-carbonyl and DPRO-3-carbonyl)-D-glucose (4 and 6) were evaluated using white radish sprouts. For each of these compounds, electron spin resonance (ESR) spectrometry was used to measure two effects: the rate of in vitro reduction via the addition of ascorbic acid; and, the rate of successful incorporation into radish sprouts for a reduction to the corresponding hydroxyl amine. DPRO-radicals 2, 5, and 6 were detected significantly more than TEMPO-radicals 1, 3, and 4 in vitro and in vivo for both experiments. Four glucose-linked nitroxide radicals were reduced faster than the glucose-non-linked ones in the in vitro experiment, but were nonetheless detected more each time in radish sprouts due to the absorbability. Glucose ester-linked radicals 4 and 6 were detected more than glycosides 3 and 5, which suggests that glucose ester-linked DPRO-radical 6 is the best for use as a spin-label probe that a plant will incorporate.