158266-30-9Relevant academic research and scientific papers
Electronic properties, polymerization, and cycloaddition of 3,4,7,8-tetragermacycloocta-1,5-diyne and related compounds
Komoriya, Haruhiko,Kako, Masahiro,Nakadaira, Yasuhiro,Kunio, Mochida,Tonogaki-Kubota, Mari,Kobayashi, Tsunetoshi
, p. 123 - 130 (2007/10/02)
Permethylated 3,4,7,8-tetragermacycloocta-1,5-diyne (1) and 3,4-disila-7,8-digermacycloocta-1,5-diyne (2) were prcpared.The photoelectron spectra of 1 and 2 were compared with that of their tetrasila analogue 3.The first ionization energy decreases in the order 3 > 2 > 1.Charge-transfer spectra of 1-tetracyanoethylene (TCNE), 2-TCNE and 3-TCNE complexes were observed.In CH2Cl2 containing TCNE 1 underwent oligomerization to give its higher homologues, and in CH3CN containing a catalytic amount of TCNE both 1 and 2 were polymerized to give the corresponding polymers almost quantitatively, whereas the sila analogue 3 was stable under these conditions.All compounds 1, 2 and 3 cycloadded to 2,3-dichloro-5,6-dicyano-1,4-benzoquinone to give the corresponding 1:1 adducts in a manner.Keywords: Germanium; Charge transfer; Group 14; Photoelectron spectroscopy; Main Group metals; Silicon
