1582792-75-3Relevant academic research and scientific papers
A series of divalent metal complexes with mixed 5-(imidazol-1-ylmethyl) isophthalic acid and N-donor ligands: Synthesis, characterization and property
Kuai, Hai-Wei,Okamura, Taka-Aki,Sun, Wei-Yin
, p. 8 - 18 (2014)
Eight complexes with different 3d metal centers and auxiliary ligands, [Cu(L)(py)] (1), [Cu(L)(bpy)]·1.5H2O (2), [Mn(L)] (3), [Mn(L)(pybim)]·3H2O (4), [Ni(L)(bpy)]·2H2O (5), [Ni(L)(phen)]·2H2O (6), [Ni(L)(bpe)(H2O)] ·2H2O (7) and [Zn(L)(bpy)]·2H2O (8) [H 2L = 5-(imidazol-1-ylmethyl)isophthalic acid, py = pyridine, bpy = 2,2′-bipyridine, pybim = 2-(pyridin-2-yl)-1H-benzo[d]imidazole, phen = 1,10-phenanthroline, bpe = 1,2-di(pyridin-4-yl)ethylene] were obtained under hydrothermal conditions and characterized by single crystal and powder X-ray diffractions, IR, elemental and thermogravimetric analyses. Complex 1 is a 3-connected uninodal 2D network with (4.82) topology, while 2, 4, 6 and 7 display 3-connected uninodal 2D network with (63) hcb topology, 3 exhibits a (5,5)-connected binodal 3D net with (45)(65) topology, 5 and 8 have 1D double-chain structures. The influence of metal centers and auxiliary ligands on the structures of resultant complexes is discussed. Magnetic property of 3 and luminescence of 8 were investigated.
