1582801-10-2

Basic information

• Product Name: dibenzofuran-4-yl(4-nitrophenyl)methanone
• Synonyms: dibenzofuran-4-yl(4-nitrophenyl)methanone
• CAS NO: 1582801-10-2
• Molecular Weight: 317.301
• Mol File: 1582801-10-2.mol

Chemical Properties

• CAS DataBase Reference: dibenzofuran-4-yl(4-nitrophenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: dibenzofuran-4-yl(4-nitrophenyl)methanone(1582801-10-2)
• EPA Substance Registry System: dibenzofuran-4-yl(4-nitrophenyl)methanone(1582801-10-2)

Safety Data

• Hazardous Substances Data: 1582801-10-2(Hazardous Substances Data)

Upstream product

• 636-98-6 p-nitrobenzene iodide 
• 100124-06-9 4-dibenzofurylboronic acid 
• 201230-82-2 carbon monoxide 

Relevant articles and documents

In situ generated nickel nanoparticle-catalyzed carbonylative Suzuki reactions of aryl iodides with arylboronic acids at ambient CO pressure in poly(ethylene glycol)

A general in situ generated nickel nanoparticle-catalyzed carbonylative Suzuki reactions of aryl iodides with arylboronic acids at atmospheric CO pressure in poly(ethylene glycol) has been demonstrated. A wide range of aryl iodides and arylboronic acids can be coupled to the corresponding biarylketones with high yields even in the absence of an added ligand and at low catalyst loading. The nature of the active catalytic species is discussed. This journal is

At normal pressure fragrant ketone nickel catalytic synthesis method

The invention discloses a method for synthesizing diarylketone under the catalysis of nickel at normal pressure. The method comprises the steps of enabling aryl iodide, arylboronic acid and carbon monoxide to be subjected to direct cross-coupling reaction in a solvent polyethylene glycol or a water solution of polyethylene glycol under the catalysis of a nickel catalyst and the combined action of alkaline and acid at normal pressure to prepare a diarylketone compound. The method has the advantages of wide catalyst source, low price, little toxicity, reaction at normal pressure, high selectivity, no need of ligands in reaction, good activity, good functional group compatibility, wide substrate application range, wide substrate source, stable substrate, green and recyclable reaction medium and the like. The separation yield of target products is up to 93% under an optimized reaction condition.

Iron-catalyzed carbonylative Suzuki reactions under atmospheric pressure of carbon monoxide

The first highly effective iron-catalyzed carbonylative Suzuki reaction has been developed. Substrates with electron-donating or electron-withdrawing functionality, ortho-substitution, as well as active groups proceeded smoothly, affording desired products in high yields. This protocol is economical, environmentally benign and practical for the synthesis of biaryl ketones. This journal is the Partner Organisations 2014.