158355-76-1

Basic information

• Product Name: (R)-3-((E)-(S)-3-Benzyloxy-oct-1-enyl)-2-methylene-cyclopentanone
• Synonyms: (R)-3-((E)-(S)-3-Benzyloxy-oct-1-enyl)-2-methylene-cyclopentanone
• CAS NO: 158355-76-1
• Molecular Weight: 312.452
• Mol File: 158355-76-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-3-((E)-(S)-3-Benzyloxy-oct-1-enyl)-2-methylene-cyclopentanone(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-3-((E)-(S)-3-Benzyloxy-oct-1-enyl)-2-methylene-cyclopentanone(158355-76-1)
• EPA Substance Registry System: (R)-3-((E)-(S)-3-Benzyloxy-oct-1-enyl)-2-methylene-cyclopentanone(158355-76-1)

Safety Data

• Hazardous Substances Data: 158355-76-1(Hazardous Substances Data)

Upstream product

• 158355-62-5 4-hydroxy-hex-5-enyl pivalate 
• 158355-69-2 Acetic acid (1R,2S)-2-benzyloxy-1-[(E)-4-(2-vinyl-[1,3]dioxolan-2-yl)-but-1-enyl]-heptyl ester 
• 158355-71-6 Acetic acid (1R,2S)-2-benzyloxy-1-[(Z)-4-(2-vinyl-[1,3]dioxolan-2-yl)-but-1-enyl]-heptyl ester 
• 158355-68-1 Acetic acid (1S,2S)-2-benzyloxy-1-[(E)-4-(2-vinyl-[1,3]dioxolan-2-yl)-but-1-enyl]-heptyl ester 
• 158355-70-5 Acetic acid (1S,2S)-2-benzyloxy-1-[(Z)-4-(2-vinyl-[1,3]dioxolan-2-yl)-but-1-enyl]-heptyl ester 
• 158355-64-7 (S)-6-Benzyloxy-1-(2-vinyl-[1,3]dioxolan-2-yl)-undec-3-yn-5-one 
• 158355-65-8 2-(4,4-Dibromo-but-3-enyl)-2-vinyl-[1,3]dioxolane 
• 158355-63-6 3-(2-Vinyl-[1,3]dioxolan-2-yl)-propionaldehyde 

Relevant articles and documents

Chirality Transfer in the Palladium(0)-Catalyzed Cyclization of 3-Oxo-8,9-dihydroxytetradeca-1,6-diene Derivatives into 2-Methylenecyclopentanones

Pd(0)-catalyzed cyclization of four diastereomeric 3-oxo-8,9-dihydroxytetradeca-1,6-diene derivatives were carried out to give 2-methylenecyclopentanones with stereospecific 1,3-chirality transfer in up to 95percent overall inversion of stereochemistry, one of which contains a correct ω-side chain to be Stork's intermidiate for prostaglandins.