1584673-27-7Relevant academic research and scientific papers
The palladium-catalyzed intermolecular C-H chalcogenation of arenes
Qiu, Renhua,Reddy, Vutukuri Prakash,Iwasaki, Takanori,Kambe, Nobuaki
, p. 367 - 374 (2015)
Palladium catalyzes the intermolecular chalcogenation of carbazole, 2-phenylpyridine, benzo[h]quinolone, and indole derivatives with disulfides and diselenides via selective C-H bond cleavage, providing a convenient route to thio and selenoethers.
Copper-mediated thiolation of carbazole derivatives and related N-heterocycle compounds
Zhu, Longzhi,Cao, Xin,Qiu, Renhua,Iwasaki, Takanori,Reddy, Vutukuri Prakash,Xu, Xinhua,Yin, Shuang-Feng,Kambe, Nobuaki
, p. 39358 - 39365 (2015)
The copper-mediated direct thiolation of carbazole derivatives with disulfides via C(sp2)-H bond cleavage was developed for synthesizing diaryl and alkyl aryl sulfides. This reaction exhibits wide tolerance toward various functional groups givi
Directed C?H Activation and Tandem Cross-Coupling Reactions Using Palladium Nanocatalysts with Controlled Oxidation
Kim, Kiseong,Jung, Younjae,Lee, Suyeon,Kim, Mijong,Shin, Dongwoo,Byun, Hyeeun,Cho, Sung June,Song, Hyunjoon,Kim, Hyunwoo
supporting information, p. 6952 - 6956 (2017/06/06)
Controlled oxidation of palladium nanoparticles provided high-valent PdIV oxo-clusters which efficiently promote directed C?H halogenation reactions. In addition, palladium nanoparticles can undergo changes in oxidation states to provide both high-valent PdIV and low-valent Pd0 species within one system, and thus a tandem reaction of C?H halogenation and cross-coupling (C?N, C?C, and C?S bond formation) was successfully established.
Rhodium-catalyzed directed sulfenylation of arene C-H bonds
Yang, Yaxi,Hou, Wei,Qin, Lihuai,Du, Juanjuan,Feng, Huijin,Zhou, Bing,Li, Yuanchao
supporting information, p. 416 - 420 (2014/04/03)
The rhodium-catalyzed intermolecular direct C-H thiolation of arenes with aryl and alkyl disulfides was developed for the first time to provide a convenient route to aryl thioethers. This strategy is compatible with many different directing groups and exhibits excellent functional group tolerance. More significantly, mono- or dithiolation can be selectively achieved, thus providing a straightforward way for selective preparation of aryl thioethers and dithioethers.
