1584673-31-3Relevant academic research and scientific papers
Pd(II)-catalyzed selective sulfenylation of arene C-H bonds using N-arylthiobenzamides as thiolation reagent and oxidant
Zhang, Xing-Song,Li, Guoxing,Zhang, Xing-Guo,Zhang, Xiao-Hong
, p. 5458 - 5464 (2015/08/03)
The palladium-catalyzed direct sulfenylation of arenes with N-arylthiobenzamides was developed for the synthesis of aryl sulfides. Additional oxidant was not required for the catalytic cycle because N-arylthiobenzamide was used as both thiolation reagent and oxidant. The selective mono- or di-sulfenylation could be controlled by addition of the amount of N-arylthiobenzamide. Excellent functional group tolerance was observed and thioethers or dithioethers were obtained in good yields.
Rhodium-catalyzed directed sulfenylation of arene C-H bonds
Yang, Yaxi,Hou, Wei,Qin, Lihuai,Du, Juanjuan,Feng, Huijin,Zhou, Bing,Li, Yuanchao
supporting information, p. 416 - 420 (2014/04/03)
The rhodium-catalyzed intermolecular direct C-H thiolation of arenes with aryl and alkyl disulfides was developed for the first time to provide a convenient route to aryl thioethers. This strategy is compatible with many different directing groups and exhibits excellent functional group tolerance. More significantly, mono- or dithiolation can be selectively achieved, thus providing a straightforward way for selective preparation of aryl thioethers and dithioethers.
