1584673-53-9Relevant academic research and scientific papers
Palladium-catalyzed direct thiolation of aryl C-H bonds with disulfides
Iwasaki, Masayuki,Iyanaga, Miki,Tsuchiya, Yuta,Nishimura, Yugo,Li, Wenjuan,Li, Zhiping,Nishihara, Yasushi
supporting information, p. 2459 - 2462 (2014/03/21)
A catalytic variant of the direct thiolation of arenes, bearing directing groups, with disulfides or thiols has been developed under palladium and copper co-catalysis. Both sulfenyl moieties of the disulfide could be incorporated into the thiolated produc
Rhodium-catalyzed directed sulfenylation of arene C-H bonds
Yang, Yaxi,Hou, Wei,Qin, Lihuai,Du, Juanjuan,Feng, Huijin,Zhou, Bing,Li, Yuanchao
supporting information, p. 416 - 420 (2014/04/03)
The rhodium-catalyzed intermolecular direct C-H thiolation of arenes with aryl and alkyl disulfides was developed for the first time to provide a convenient route to aryl thioethers. This strategy is compatible with many different directing groups and exhibits excellent functional group tolerance. More significantly, mono- or dithiolation can be selectively achieved, thus providing a straightforward way for selective preparation of aryl thioethers and dithioethers.
