158500-18-6Relevant articles and documents
Syntheses of novel fullerene tweezers and their supramolecular inclusion complex of C60
Matsubara, Hiroshi,Shimura, Tomohiro,Hasegawa, Akio,Semba, Miki,Asano, Kaori,Yamamoto, Koji
, p. 1099 - 1100 (1998)
Fullerene tweezers which have a rigid acetylenic spacers were synthesized and their inclusion abilities for C60 were examined by UV spectroscopy. From the spectra, the association constants were determined using Benesi-Hildebrand method. Fullerene tweezers with a 1,4-bis(4-oxycarbonylphenyl)butadiyne spacer showed the highest association constant for C60 (39300±250 dm3mol-1 in benzene).