158587-49-6

Upstream product

• 158587-48-5 (S)-4-Benzyl-3-{(2S,3R)-6-benzyloxy-2-[(S)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-3-hydroxy-hexanoyl}-oxazolidin-2-one 
• 158587-47-4 (S)-4-Benzyl-3-[(S)-4-(tert-butyl-diphenyl-silanyloxy)-3-methyl-butyryl]-oxazolidin-2-one 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 158587-60-1 (3S,4S)-3-((R)-4-Benzyloxy-1-hydroxy-butyl)-4-methyl-dihydro-furan-2-one 
• 136262-53-8 (3S)-4-[(tert-butyldiphenylsilyl)oxy]-3-methylbutanenitrile 
• 123444-68-8 (S)-4-(tert-butyldiphenylsilyloxy)-3-methylbutanal 
• 1000596-44-0 4-(tert-butyldiphenylsilyloxy)-3S-methylbutanoic acid 
• 5470-84-8 4-benzyloxybutanal 

Downstream Products

• 158587-55-4 (4S,5R,6R)-4-Azido-9-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-5-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-nonanoic acid methyl ester 
• 158587-54-3 (4S,5R,6R)-4-Azido-9-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-5-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-nonanoic acid 
• 158587-53-2 (4S,5R,6R)-4-Azido-9-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-5-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-nonanal 
• 158587-52-1 {(4R,5R,6S)-6-Azido-4-(tert-butyl-dimethyl-silanyloxy)-5-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-dec-9-enyloxymethyl}-benzene 
• 158587-61-2 Methanesulfonic acid (1R,2S,3R)-6-benzyloxy-1-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxy)-2-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-hexyl ester 
• 158587-56-5 (S)-5-{(1R,2R)-5-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-pentyl}-pyrrolidin-2-one 
• 158587-50-9 (6S,7R)-10-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-6-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-dec-1-en-5-one 
• 158587-51-0 (5R,6R,7R)-10-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-6-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-dec-1-en-5-ol 
• 794528-61-3 (1S,3aR,10aS,10bR)-1-methyloctahydro-2H-furo[3,2-c]pyrrolo[1,2-a]azepine-2,8(1H)-dione 
• 609817-36-9 (Z)-(4R,5R,12S)-1-benzyloxy-4-(tert-butyldimethylsilanyloxy)-5-[(S)-2-(tert-butyldimethylsilanyloxy)-1-methylethyl]-13-methoxymethoxy-12-methyltridec-9-en-6-one 

Relevant academic research and scientific papers

Total Synthesis of (-)-Stemoamide

An enantiocontrolled total synthesis of the tricyclic alkaloid, stemoamide (2), is reported. Key Words: Asymmetric aldol; chiral butyrolactone synthesis; selective 1,3-acyclic diol formation.