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CAS

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158587-79-2

(E)-(2R,3R)-3-(Dimethyl-phenyl-silanyl)-2-methyl-hex-4-en-1-ol is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 158587-79-2 Structure

  • Basic information

    1. Product Name: (E)-(2R,3R)-3-(Dimethyl-phenyl-silanyl)-2-methyl-hex-4-en-1-ol
    2. Synonyms: (E)-(2R,3R)-3-(Dimethyl-phenyl-silanyl)-2-methyl-hex-4-en-1-ol
    3. CAS NO:158587-79-2
    4. Molecular Formula:
    5. Molecular Weight: 248.44
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 158587-79-2.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (E)-(2R,3R)-3-(Dimethyl-phenyl-silanyl)-2-methyl-hex-4-en-1-ol(CAS DataBase Reference)
    10. NIST Chemistry Reference: (E)-(2R,3R)-3-(Dimethyl-phenyl-silanyl)-2-methyl-hex-4-en-1-ol(158587-79-2)
    11. EPA Substance Registry System: (E)-(2R,3R)-3-(Dimethyl-phenyl-silanyl)-2-methyl-hex-4-en-1-ol(158587-79-2)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 158587-79-2(Hazardous Substances Data)

158587-79-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 158587-79-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,8,5,8 and 7 respectively; the second part has 2 digits, 7 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 158587-79:
(8*1)+(7*5)+(6*8)+(5*5)+(4*8)+(3*7)+(2*7)+(1*9)=192
192 % 10 = 2
So 158587-79-2 is a valid CAS Registry Number.

158587-79-2Relevant articles and documents

Diastereoselectivity in cyclopropanation and epoxidation reactions of chiral (E)-crotylsilanes: Asymmetric synthesis of substituted tetrahydrofurans

Panek, James S.,Garbaccio, Robert M.,Jain, Nareshkumar F.

, p. 6453 - 6456 (1994)

Functionalized (E)-crotylsilanes 1 bearing a bis-homoallytic hydroxyl group undergo diastereoselective cyclopropanation and epoxidation reactions to produce substituted tetrahydrofurans 3 and 5 respectively after an acid catalyzed heterocyclization.

Asymmetric C-N bond constructions via crotylsilane addition reactions: A stereocontrolled route to dipeptide isosteres

Masse, Craig E.,Knight, Bradford S.,Stavropoulos, Pericles,Panek, James S.

, p. 6040 - 6047 (2007/10/03)

A new approach to the asymmetric synthesis of (E)-olefin dipeptide isosteres is described based on asymmetric C-N bond constructions resulting from nitronium tetrafluoroborate (NO2BF4) promoted electrophilic nitrations of chiral (E)-crotylsilanes and from a copper(I)-catalyzed enantioselective aziridination of chiral (E)-crotylsilanes. The silane reagents undergo efficient anti-S(E)' additions to the nitrogen-based electrophiles to give the (E)-olefin isosteves in > 96% de. The topological bias is principally controlled by the facial bias of the silane reagent. The scope of the methodology was explored via several related crotylsilane derivatives. The (E)-olefin isosteres are nonhydrolyzable, rigid analogs of the peptide linkage in biologically active peptides. The new methodology will facilitate the preparation and study of peptidomimetics since the crotylsilane reagents allow for incorporation of a wide range of functionality on the resulting isosteres.

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