1585977-37-2Relevant academic research and scientific papers
Synthetic exploitation of halogenated alkenes containing an electron-withdrawing group: Synthesis of α-chlorohydrazones and ketene aminals by regiospecific reactions of in situ generated imide chlorides
Tuyun, Amac Fatih
supporting information, p. 2085 - 2089 (2014/04/03)
A concise approach for the construction of ketene aminals and α-chlorohydrazones has been developed. It involves reactions of the regiodefined gem-dihalo nitrovinyl compound of in situ generated imide chlorides in different media with primary arylamines being dependent on the aryl groups. A range of ketene aminals and α-chlorohydrazones are obtained in good to high yields. In addition, α-aminohydrazones are prepared by using α-chlorohydrazones as the precursors.
