158640-92-7Relevant articles and documents
PREPARATION AND PROPERTIES OF THE BENZYL COMPLEXES 3P)Pt(μ-X)2Pt(P3)(CH2C6H5)> (X = OH, Br)
Rizzi, Gian Andrea,Morandini, Franco,Turco, Aldo
, p. 213 - 216 (2007/10/02)
The compound 2 has been prepared by the action of benzyl Grignard reagents on the bridged dinuclear complexes in diethyl ether/tetrahydrofuran.Reaction of the hydroxo complex with sodium bromide in toluene/water yielded the corresponding dinuclear bromide complex.Both complexes have been characterized by NMR (1H, 31P) and IR spectroscopy, and possess the η1 structure.This is compared with the η3-structure of the palladium homologue 2.