15870-10-7Relevant articles and documents
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Schlosser,M. et al.
, p. 1567 - 1576 (1974)
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Engineering active sites on reduced graphene oxide by hydrogen plasma irradiation: Mimicking bifunctional metal/supported catalysts in hydrogenation reactions
Primo, Ana,Franconetti, Antonio,Magureanu, Monica,Mandache, Nicolae Bogdan,Bucur, Cristina,Rizescu, Cristina,Cojocaru, Bogdan,Parvulescu, Vasile I.,Garcia, Hermenegildo
, p. 2611 - 2623 (2018/06/18)
H2 plasma has been used to generate carbon vacancies on reduced graphene oxide to increase its catalytic activity as a hydrogenation catalyst. A relationship between the power of the plasma treatment and the exposure time with the activity of the material was observed for CC double bond hydrogenation. The activity data in the case of 1-octene, showing skeletal isomerization besides hydrogenation, indicate that H2 plasma treatment can introduce hydrogenating and acid sites rendering a bifunctional catalyst that is reminiscent of the activity of noble metals supported on acid supports.
Molybdenum carbonyl grafted onto silicate intercalated cobalt-aluminum hydrotalcite: A new potential catalyst for the hydroformylation of octene
Sakthivel, Ayyamperumal,Mahato, Nihar Ranjan,Baskaran, Thangaraj,Christopher, Jayaraj
, p. 55 - 61 (2015/04/27)
We present the first example of molybdenum carbonyl grafted on diaminosiloxane-functionalized cobalt-aluminum hydrotalcite (CA-HTSi-DA-Mo) as a promising catalyst for the hydroformylation of olefins. The catalyst showed 80% conversion with selective formation of branched aldehyde. About 70% of the catalytic activity retains even after three cycles.
A remarkable catalytic activity of [Cu(NCMe)2(PPh 3)2]BF4 in conjugate addition of organomanganese reagents to α,β-unsaturated ester, enone and allyl chloride
Deshmukh,Jadhav, Sunil,Anbhule,Mali,Suryawanshi
, p. 248 - 250 (2007/10/03)
A simple and convenient method of conjugate addition of alkyl and aryl organomanganese reagents to α,β-unsaturated ester and enone and allyl chloride in presence of Cu(I) salts is described. Conjugated products result with [Cu(NCMe)2(PPh3)2]BF4 as a catalyst along with chlorosilane as an accelerator at -10 to 0 °C.
