15871-09-7Relevant academic research and scientific papers
DISPROPORTIONIERUNGEN VON DIPHENYLDISULFIDEN ZU 1.2-BENZISOTHIAZOLEN UND o-SUBSTITUIERTEN THIOPHENOLEN UNTER ANCHIMERER BETEILIGUNG VON ORTHOSTAENDIGEN AMID-, THIOAMID- UND AMIDIN-GRUPPEN
Boeshagen, H.,Geiger, W.
, p. 325 - 330 (2007/10/02)
Substituents in the ortho position provide anchimeric support in the dissociation of diphenylsulphides.The carbamoyl group has only a weak effect.Support increases from an N,N'-disubstituted guanyl group, over thioamide to a guanyl group with an unsubstituted nitrogen atom, which effects an almost completely reversible cleavage of the disulphide group.
