158746-88-4Relevant academic research and scientific papers
Transition-metal-free homocoupling of 1-haloalkynes: A facile synthesis of symmetrical 1,3-diynes
Chen, Zhengwang,Jiang, Huanfeng,Wang, Azhong,Yang, Shaorong
, p. 6700 - 6703 (2010)
Symmetrical 1,3-diyne compounds can be easily synthesized via a transition-metal-free homocoupling reaction of 1-haloalkynes without base and oxidant. The method shows excellent functional group compatibility and high yields.
A mild CuI-catalyzed Glaser-type homo-coupling reaction using α,α-dibromo-β-dicarbonyl compounds as oxidants
Fan, Xiaohui,Li, Na,Shen, Tong,Cui, Xiao-Meng,Lv, Hao,Zhu, Hong-Bo,Guan, Yong-Hong
supporting information, p. 256 - 261 (2014/01/06)
Exploration of α,α-dibromo-β-dicarbonyl compounds as novel organic oxidants for the mild Cu(I)-catalyzed Glaser-type homo-coupling reaction has been achieved, which provides an alternatively efficient pathway for the construction of 1,3-conjugated structures. In addition, the mechanism of this reaction was investigated.
