158783-73-4Relevant academic research and scientific papers
Assignment of the Absolute Configuration of the Siphonarins and Baconipyrones. Enantiocontrolled Synthesis of a γ-Pyrone Subunit.
Paterson, Ian,Franklin, Alison S.
, p. 6925 - 6928 (1994)
Aldehyde 11 was prepared with >90percent ds using a Sn(II)-mediated aldol reaction between (S)-13 and (S)-14.Conversion into the γ-pyrone 8, a known degradation product from dihydrosiphonarin B, established the absolute configuration as enantiomeric to th
