158784-57-7Relevant academic research and scientific papers
Digermylplatinum(II) organometallic rings L2PtGe(Me2)EGeMe2 [E = N-, O, S, (η-C5H4)2Fe]
Barrau,Rima,Cassano,Satgé
, p. 5700 - 5703 (2008/10/09)
The synthesis, reactivity, and characterization of the digermylplatinum(II) linear complexes (ClMe2Ge)2Pt(PPh3)2 (1) and (ClMe2Ge)2Pt(diphos) (2) and cyclic complexes (diphos)PtGe-(Me2)EGeMe2 [E = S (3), -NPh (4), (η5-C5H4)Fe(η5-C 5H4) (5), O (6)] are reported. The chemistry of 2-6 is illustrated through their reactions with phenylacetylene and N-methyltriazolinedione. Complexes 3 and 6 give double germylation of these unsaturated systems, while 2, by reaction with triazolinedione, gives the monogermylated complex Me2-(Cl)GePt(Cl)diphos and the dimer of the germylated heterocycle Me2GeNC(O)N(Me)C(O)N.
