158813-41-3Relevant academic research and scientific papers
Reactions of α-haloallyllithium derivatives with carbon, silicon, tin or boron halides and carbonyl compounds
Julia, Marc,Verpeaux, Jean-Noel,Zahneisen, Thomas
, p. 539 - 554 (2007/10/02)
A series of allylic halides have been converted into their α-carbanions with strong lithium bases, using different techniques.These have been compared in their reaction with various electrophiles leading to functionally substituted allyl derivatives.The influence of the counterion on the regio- and stereoselectivity has been investigated. allylic halides / α-halocarbanions / allylsilanes / allyltin derivatives / α-chlorohydrins / vinylepoxides / diastereoselectivity
ACTION DU CHLOROALLYLLITHIUM SUR LES ALDEHYDES ET LES CETONES: SYNTHESE EN UNE ETAPE D'ALCOOLS β-ETHYLENIQUES γ-CHLORES DE CONFIGURATION Z ET D'EPOXYDES α-ETHYLENIQUES BI- OU TRI-SUBSTITUES
Doucoure, A.,Mauze, B.,Miginiac, L.
, p. 139 - 148 (2007/10/02)
Chloroallyllithium readily reacts with aliphatic and aromatic aldehydes and ketones to produce, in a one-step reaction, Z-γ-chlorinated-β-ethylenic alcohols and bi- or tri-substituted epoxides.
