158835-62-2Relevant academic research and scientific papers
Hydroxyalkylphosphines in Asymmetric Hydrogenations
Holz, Jens,Boerner, Armin,Kless, Achim,Borns, Susanne,Trinkhaus, Stephan,et al.
, p. 1973 - 1988 (2007/10/03)
The synthesis of chiral bisphosphines bearing a hydroxyl group in a rigid backbone is described.These compounds which are analogues of the prominent ligand DIOP formed definite rhodium complexes.IR spectra provided evidence that the hydroxyl groups do not
Synthesis of an optically active hydroxy diphosphine, a new ligand for asymmetric catalysis
Boerner, Armin,Holz, Jens,Kless, Achim,Heller, Detlef,Berens, Ulrich
, p. 6071 - 6074 (2007/10/02)
The synthesis of (4R, 5R)-4,5-bis(diphenylphosphinomethyl)-2-hydroxymethyl-2-phenyl-1,3-diox olane 1 which is related to DIOP is described. The application of this new ligand in asymmetric catalysis is illustrated in the stereodifferentiating hydrogenation.
