158979-46-5

Upstream product

• 619-73-8 4-nitrobenzyl chloride 
• 3068-34-6 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-chloro-tetrahydro-pyran-4-yl ester 
• 10378-06-0 2-methyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranoso)[1,2-d]-2-oxazoline 

Downstream Products

• 158979-50-1 6-Acryloylamino-hexanoic acid [4-((2R,3R,4R,5S,6R)-3-acetylamino-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxymethyl)-phenyl]-amide 
• 158979-48-7 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-[4-(6-acryloylamino-hexanoylamino)-benzyloxy]-tetrahydro-pyran-4-yl ester 
• 158979-47-6 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-(4-acryloylamino-benzyloxy)-tetrahydro-pyran-4-yl ester 
• 210423-90-8 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-1-O-[p-(n-decanamido)benzyl]-β-D-glucopyranoside 

Relevant academic research and scientific papers

The synthesis of glycosides of 2-acetamido-2-deoxyglucose catalyzed by mercuric iodide

The glycosylation of various alcohols with peracetylated α-D-glucosaminyl chloride catalyzed with mercuric iodide was studied along with the dependence of the reaction course on temperature, solvent, and quantity of catalyst. At room temperature, only β-glycosides of peracetylated N-acetylglucosamine were shown to result in dichloroethane or nitromethane with high yields. At 90-95°C, anomerization was observed, which led to the corresponding α-glycosides. The possibility of the synthesis of disaccharides with the β1→6 bond catalyzed by mercuric iodide was demonstrated.

High performance polymer supports for enzyme-assisted synthesis of glycoconjugates

Efficient and practical methodology for the construction of carbohydrates, including oligosaccharide derivatives and sphingoglycolipids, was established on the basis of a watersoluble polymer supports having unique linkers that can be cleaved by specific

Synthesis and modification of spacered glycosides of N-acetylglucosamine

From glucosaminyl chloride peracetate, in the presence of HgI2, we have obtained β-p-nitrobenzyl-, β-ω-chloro-and β-ω-azido-spacered glycosides of N-acetylglucosamine (NAG) with spacers of different lengths and chemical natures. The correspondi

Chemoenzymatic oligosaccharide synthesis on a soluble polymeric carrier

A facile and efficient method for the chemical and enzymatic syntheses of oligosaccharides using a new type of soluble polymeric sugar acceptor substrate is described. The water soluble glycopolymers having N-acetyl-D- glucosamine (GlcNAc) branches derive