15898-52-9Relevant academic research and scientific papers
Cathodic reductive coupling of methyl cinnamate on boron-doped diamond electrodes and synthesis of new neolignan-type products
Kojima, Taiki,Obata, Rika,Saito, Tsuyoshi,Einaga, Yasuaki,Nishiyama, Shigeru
, p. 200 - 203 (2015)
The electroreduction reaction of methyl cinnamate on a boron-doped diamond (BDD) electrode was investigated. The hydrodimer, dimethyl 3,4-diphenylhexanedioate (racemate/meso = 74:26), was obtained in 85% yield as the major product, along with small amounts of cyclic methyl 5-oxo-2,3-diphenylcyclopentane-1-carboxylate. Two new neolignan-type products were synthesized from the hydrodimer.
Stereoselective hydrocoupling of [(1R)-exo]-3-exo-(diphenylmethyl)bornyl cinnamates by electroreduction
Kise, Naoki,Iwasaki, Keisuke,Tokieda, Naohiko,Ueda, Nasuo
, p. 3241 - 3244 (2007/10/03)
Equation presented The chiral auxiliary [(1R)-exo]-3-exo-(diphenylmethyl)borneol, synthesized from (1R)-(+)-camphor in three steps, was highly effective for the stereoselective hydrocoupling of its cinnamates by electroreduction. From the resulting hydrod
PHOTOINDUCED OXIDATIVE CLEAVAGE OF ARYLCYCLOPROPANES IN THE PRESENCE OF ORGANIC ELECTRON-ACCEPTOR
Mizuno, Kazuhiko,Ogawa, Jun,Otsuji, Yoshio
, p. 741 - 744 (2007/10/02)
The cyclopropane ring of arylcyclopropanes is oxidatively cleaved by irradiation in polar solvents containing nucleophiles such as alcohols, water, and sodium cyanide in the presence of electron-acceptor such as 1,4-dicyanobenzene and 1-cyanonaphthalene, giving nucleophile-incorporated products.This photoreaction proceeds via an electron-transfer from the cyclopropanes to the excited electron-acceptors, and the cation radicals of arylcyclopropanes are involved as key intermediates.
Reductive Rearrangement of 4-Phenyl-1,3-dioxans to 2-Phenylbutane-1,4-diols upon Treatment with Sodium-Potassium Alloy
Bailey, William F.,Cioffi, Eugene A.
, p. 155 - 156 (2007/10/02)
Reduction of 4-phenyl-1,3-dioxan with Na-K alloy affords 2-phenylbutane-1,4-diol as the major product along with smaller amounts of 3-phenylpropan-1-ol and 3,4-diphenylhexane-1,6-diols.
