15900-51-3Relevant articles and documents
General base-tuned unorthodox synthesis of amides and ketoesters with water
Khamarui, Saikat,Maiti, Rituparna,Maiti, Dilip K.
supporting information, p. 384 - 387 (2015/01/09)
We discovered a highly reactive λ3-hypervalent iodane species using an inorganic/organic base for the unorthodox synthesis of amides and ketoesters through grafting terminal alkynes. In contrast to the metal-catalyzed dehydrative approaches the in situ generated nonmetallic reagent efficiently created C-N/C-O and CO bonds with amines/alkynes and water at rt. This journal is