1590412-34-2Relevant academic research and scientific papers
A 1-D Cd(II) complex based on 2-(1 H -imidazole-1- ylmethyl)-1 H -benzimidazole and 1,3,5- benzenetricarboxylate
Wang, Xiuxiu,Han, Xiao,Yang, Yang,Meng, Xiangru
, p. 462 - 468 (2014)
A new complex, {[CdCl(H2btc-)(imb)]·H 2O}n (1), has been synthesized through the reaction of CdCl2·2.5H2O with ligands 2-(1H-imidazole-1- ylmethyl)-1H-benzimidazole (imb) and 1,3,5-benzenetricarboxylic acid (H 3btc) in water at 80°C. Single-crystal X-ray diffraction analysis shows that complex 1 exhibits 1-D double-stranded chain in which two Cd(II) ions are bridged by two carboxyl groups from two benzenetricarboxylates. These 1-D double-stranded chains are further stacked via hydrogen bonds and the π-π interactions leading to 3-D structure. A thermogravimetric analysis was carried out and the fluorescent property of the complex was investigated. Supplemental materials are available for this article. Go to the publisher's online edition of Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry to view the supplemental file. Copyright Taylor & Francis Group, LLC.
