15910-22-2Relevant academic research and scientific papers
Unsaturated-compound hydrogenation nanocatalysts based on palladium and platinum particles immobilized in pores of mesoporous aromatic frameworks
Kulikov,Terenina,Kryazheva, I. Yu.,Karakhanov
, p. 222 - 229 (2017/04/07)
Heterogeneous catalysts for the hydrogenation of unsaturated hydrocarbons have been synthesized on the basis of palladium and platinum nanoparticles immobilized in pores of mesoporous aromatic frameworks, which represent a new class of carbon supports with a diamond-like ordered structure. The resulting materials have been characterized by transmission electron microscopy, IR spectroscopy, and NMR spectroscopy. It has been shown that the catalyst activity in the hydrogenation reaction depends on the substrate molecule size and adsorbability on the surface of nanoparticles. Catalytic activity has been studied in the hydrogenation of a number of unsaturated compounds at temperatures of 60 and 80°C and pressures of 1.0 and 3.0 MPa.
METHOD FOR THE PRODUCTION OF OLEFINS COMPRISING 8 TO 12 CARBON ATOMS
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Page/Page column 32-33, (2010/02/13)
The invention relates to the production of olefins or olefin mixtures comprising 8 to 12 carbon atoms by means of a four-stage synthesis from one or several olefins containing 4 to 6 carbon atoms. Said four-stage synthesis encompasses the steps of hydroformylation to obtain aldehyde, hydrogenation to obtain alcohol, dehydration to obtain 1-olefin, and metathesis. The obtained C8 to C12 olefins can be used for the production of plasticizer alcohols, for example, particularly isononanol.
