159151-70-9

Upstream product

• 768-33-2 phenyldimethylsilyl chloride 
• 159247-81-1 [(1S,2S)-2-(Dimethyl-phenyl-silanyl)-cyclopropyl]-methanol 
• 126361-99-7 (Z)-3-(dimethyl-phenyl-silanyl)-prop-2-en-1-ol 

Relevant academic research and scientific papers

First Catalytic and Enantioselective Synthesis of Silyl and Stannyl Substituted Cyclopropylmethanols

Optically active silyl and stannyl substituted cyclopropylmethanols were effectively obtained by the catalytic and enantioselective cyclopropanation of γ-silyl and γ-stannyl substituted allylic alcohols with Et2Zn and CH2I2 in the presence of chiral N,N'-bis(p-nitrobenzenesulfonyl)-1,2-cyclohexanediamine in good enantioselectivites.The absolute configurations of the resulting metallocyclopropanes were unambiguously established.