159152-12-2Relevant articles and documents
One-Pot Synthetic Approach toward Porphyrinatozinc and Heavy-Atom Involved Zr-NMOF and Its Application in Photodynamic Therapy
Zhou, Le-Le,Guan, Qun,Li, Yan-An,Zhou, Yang,Xin, Yu-Bin,Dong, Yu-Bin
, p. 3169 - 3176 (2018/03/26)
Herein, we report an iodine-attached Zn(II)-porphyrinic dicarboxylic building block (ZnDTPP-I2-2H, 1) that can be introduced into UiO-66 NMOF via one-pot synthetic approach to generate a new ZnDTPP-I2 doped UiO-66 type nano metal-organic framework (NMOF) of ZnDTPP-I2?UiO-66 (2). Compared to its homologous iodine-free NMOF of ZnDTPP?UiO-66 (4), ZnDTPP-I2?UiO-66 (2) with heavy iodine atoms is a more effective nanosized photosensitizer for singlet oxygen generation under physiological conditions. As expected, 2 displayed a high photodynamic therapy efficacy for treatment of liver cancer cells in vitro.
Synthesis of swallowtail-substituted multiporphyrin rods
Thamyongkit, Patchanita,Lindsey, Jonathan S.
, p. 5796 - 5799 (2007/10/03)
The availability of multiporphyrin arrays with defined architectures and good solubility in organic solvents is essential for a wide variety of physical studies. Herein the synthesis of linear multiporphyrin arrays (triads, tetrad, pentad) bearing solubil
Design and synthesis of light-harvesting rods for intrinsic rectification of the migration of excited-state energy and ground-state holes
Loewe, Robert S.,Lammi, Robin K.,Diers, James R.,Kirmaier, Christine,Bocian, David F.,Holten, Dewey,Lindsey, Jonathan S.
, p. 1530 - 1552 (2007/10/03)
We present the design of molecular materials for ultimate use in solid-state solar cells. The molecular materials are semi-rigid oligomeric rods of defined length with metalloporphyrins in the backbone and a carboxy group at one end for attachment to a su
