1591916-46-9Relevant articles and documents
Asymmetric Domino Heck/Dearomatization Reaction of β-Naphthols to Construct Indole-Terpenoid Frameworks
Wang, Dong-Chao,Cheng, Peng-Peng,Yang, Ting-Ting,Wu, Pan-Pan,Qu, Gui-Rong,Guo, Hai-Ming
supporting information, p. 7865 - 7872 (2021/10/20)
A palladium-catalyzed enantioselective Heck cyclization/dearomatization cascade via capturing the cyclized Heck π-allylpalladium intermediate by β-naphthols is reported, which provides a new strategy for the construction of chiral indole-terpenoid framewo
Palladium-Catalyzed Allenamide Carbopalladation/Allylation with Active Methine Compounds
Zhu, Xiaoyi,Li, Ruibo,Yao, Hequan,Lin, Aijun
, p. 4630 - 4634 (2021/06/28)
A palladium-catalyzed allenamide carbopalladation/allylation with active methine compounds has been developed. Various indoles and isoquinolinones bearing a quaternary carbon center were achieved with good efficiency, a broad substrate scope and good functional group tolerance. This reaction underwent cascade oxidative addition, carbopalladation, and allylic alkylation, and two new C-C bonds were formed in one pot.
Indole acetyl imino sulfone series compound and preparation method thereof
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Paragraph 0030; 0129-0133, (2021/07/28)
The invention provides an indole acetyl imino sulfone series compound and a preparation method thereof. According to the preparation method, by taking ortho-halogen substituted arylamine, propargyl halide and sulfoxide sulfimide as reaction substrates, re
Tris(trimethylsilyl)silane and visible-light irradiation: A new metal- and additive-free photochemical process for the synthesis of indoles and oxindoles
Da Silva, Gustavo Piva,Ali, Akbar,Da Silva, Rodrigo César,Jiang, Hao,Paix?o, Márcio W.
supporting information, p. 15110 - 15113 (2015/10/12)
A combined tris(trimethylsilyl)silane and visible-light-promoted intramolecular reductive cyclization protocol for the synthesis of indoles and oxindoles has been developed. This straightforward and efficient method shows tolerance towards a broad spectru
An approach to cyclohepta[ b ]indoles through an allenamide (4 + 3) cycloaddition-grignard cyclization-chugaev elimination sequence
He, Shuzhong,Hsung, Richard P.,Presser, William R.,Ma, Zhi-Xiong,Haugen, Bryan J.
, p. 2180 - 2183 (2014/05/06)
A strategy for synthesizing highly functionalized cyclohepta[b]indoles through a concise (4 + 3) cycloaddition-cyclization-elimination sequence is described. The cycloaddition features nitrogen-stabilized oxyallyl cations derived from epoxidations of N-ar
