1591950-96-7Relevant academic research and scientific papers
Trapping of azidocarbenium ion: A unique route for azide synthesis
Pramanik, Suman,Ghorai, Prasanta
, p. 2104 - 2107 (2014/05/06)
For the first time, a sensitive azidocarbenium ion intermediate has been trapped with various nucleophiles to provide azides in excellent chemoselectivity. This provides a novel approach for the chemoselective synthesis of primary and secondary benzyl azides from aldehydes in a one-pot reaction. Enantioselective nucleophilic addition to the azidocarbenium ion has also been initiated.
