1592601-58-5Relevant academic research and scientific papers
Functionalisable N-heterocyclic carbene-triazole palladium complexes and their application in the suzuki-miyaura reaction
Gogolieva, Ganna,Bonin, Hélène,Durand, Jér?me,Dechy-Cabaret, Odile,Gras, Emmanuel
supporting information, p. 2088 - 2094 (2014/05/06)
Seven functionalised N-heterocyclic carbene (NHC) ligands and their corresponding palladium(II) complexes have been synthesised with a triazole moiety as a modular and stable linkage between the catalytic centre and the secondary functional group. The complexes were prepared in good yields and fully characterised by NMR spectroscopy, mass spectrometry and X-ray crystallography. The complexes are active in the Suzuki-Miyaura cross-coupling reaction, with catalytic activities maintained whatever the triazolyl substituent. This opens the possibility for various functionalisations of NHC-palladium complexes. New functionalised N-heterocyclic carbene ligands and their corresponding palladium(II) complexes have been synthesised and fully characterised. The use of a triazole moiety as a modular and stable linkage between the catalytic centre and a targeted functionalisation does not damage the catalytic activity. Copyright
Functionalisable N-heterocyclic carbene-triazole palladium complexes and their application in the Suzuki-Miyaura reaction
Gogolieva, Ganna,Bonin, Hélène,Durand, Jér?me,Dechy-Cabaret, Odile,Gras, Emmanuel
, p. 2088 - 2094 (2015/04/27)
Seven functionalised N-heterocyclic carbene (NHC) ligands and their corresponding palladium(II) complexes have been synthesised with a triazole moiety as a modular and stable linkage between the catalytic centre and the secondary functional group. The com
