1592889-83-2

Upstream product

• 402-43-7 p-trifluoromethylphenyl bromide 
• 1592890-75-9 (E)-1-(4-(trifluoromethyl)phenyl)but-2-en-1-yl acetate 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 205108-18-5 (E)-1-(buta-1,3-dien-1-yl)-4-(trifluoromethyl)benzene 

Relevant academic research and scientific papers

Nickel-catalyzed allyl-allyl coupling reactions between 1,3-dienes and allylboronates

A regiospecific allyl-allyl coupling reaction between 1,3-dienes and allylboronates has been demonstrated under nickel catalysis. Salient features of this method include the earth-abundant metal catalyst, excellent regioselectivity and good functional group tolerance. Notably, even congested allyl substrates can also be applied to this protocol, thus allowing for the rapid preparation of a series of valuable 1,5-dienes. This journal is

Catalytic stereospecific allyl-allyl cross-coupling of internal allyl electrophiles with allylB(pin)

Application of internal electrophiles in catalytic stereospecific allyl-allyl cross-coupling enable the rapid construction of multisubstituted 1,5-dienes, including those with all carbon quaternary centers. Compounds with minimal steric differentiation ca