1592980-07-8

Basic information

• Product Name: diisopropyl 2-hydroxy-3-bromo-(2-(3-diisopropyl-phosphoryl-4-hydroxy-5-bromophenyl)propan-2-yl)phosphonate
• Synonyms: diisopropyl 2-hydroxy-3-bromo-(2-(3-diisopropyl-phosphoryl-4-hydroxy-5-bromophenyl)propan-2-yl)phosphonate
• CAS NO: 1592980-07-8
• Molecular Weight: 714.365
• Mol File: 1592980-07-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diisopropyl 2-hydroxy-3-bromo-(2-(3-diisopropyl-phosphoryl-4-hydroxy-5-bromophenyl)propan-2-yl)phosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: diisopropyl 2-hydroxy-3-bromo-(2-(3-diisopropyl-phosphoryl-4-hydroxy-5-bromophenyl)propan-2-yl)phosphonate(1592980-07-8)
• EPA Substance Registry System: diisopropyl 2-hydroxy-3-bromo-(2-(3-diisopropyl-phosphoryl-4-hydroxy-5-bromophenyl)propan-2-yl)phosphonate(1592980-07-8)

Safety Data

• Hazardous Substances Data: 1592980-07-8(Hazardous Substances Data)

Upstream product

• 1809-20-7 diisopropyl hydrogenphosphonate 
• 79-94-7 Tetrabromobisphenol A 

Relevant articles and documents

Stereoselective synthesis of phosphoryl-substituted phenols

Copper-catalyzed C-X activation-phosphorylation of aryls bearing different groups has been achieved using P(O)-H compounds as efficient phosphorylation reagents without the assistance of any ligand. Optically active H-phosphinates can also act as good substrates in the reaction, giving the (Sp)-phosphoryl substituted phenolic compounds stereospecifically with retention of configuration at the phosphorus center. Furthermore, it is shown that the migration of phosphorus on O-aryl phosphonates from oxygen to carbon also proceeds stereospecifically to produce the corresponding optically active (Rp)-phosphoryl-substituted phenolic compounds with retention of configuration at phosphorus via treatment with lithium diisopropylamide (LDA). Plausible mechanisms have been proposed for these reactions.