15942-22-0Relevant academic research and scientific papers
Pd(OAc)2-catalyzed dinitration reaction of aromatic amines
Feng, Yi-Si,Mao, Long,Bu, Xiao-Song,Dai, Jian-Jun,Xu, Hua-Jian
, p. 3827 - 3832 (2015/06/02)
Taking advantage of Pd(OAc)2-catalyzed dinitration reactions with Bi(NO3)3·5H2O in trifluoroethanol (TFE) and trifluoroacetic acid (TFA), we have developed an efficient and practical method for the synthesis of secondary dinitro-aromatic amines. The products could be applied to the preparation of 5-amine-N-methyl-benzimidazolone, the azo-dyes, economic advantages. The method has also been expanded to the dinitration reaction of some tertiary aromatic amines.
STRUCTURE AND PROPERTIES OF PYRAZOLINEDIAZONIUM SALTS
Gorelik, M. V.,Titova, S. P.,Rybinov, V. I:
, p. 773 - 781 (2007/10/02)
Study of the IR spectra and reactivity of 1-R-2-pyrazoline-3-diazonium salts indicated the presence of effective electronic interaction between the RN1 group and the diazonium group.In azo coupling and nucleophilic substitution reactions of the
