159470-37-8

Basic information

• Product Name: 5-([2-(ALLYLOXY)PHENYL]METHYLENE)-1,3-DIMETHYL-2,4,6(1H,3H,5H)-PYRIMIDINETRIONE
• Synonyms: 5-([2-(ALLYLOXY)PHENYL]METHYLENE)-1,3-DIMETHYL-2,4,6(1H,3H,5H)-PYRIMIDINETRIONE;1,3-dimethyl-5-{[2-(prop-2-en-1-yloxy)phenyl]methylidene}-1,3-diazinane-2,4,6-trione
• CAS NO: 159470-37-8
• Molecular Formula: C₁₆H₁₆N₂O₄
• Molecular Weight: 300.31
• Mol File: 159470-37-8.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 5-([2-(ALLYLOXY)PHENYL]METHYLENE)-1,3-DIMETHYL-2,4,6(1H,3H,5H)-PYRIMIDINETRIONE(CAS DataBase Reference)
• NIST Chemistry Reference: 5-([2-(ALLYLOXY)PHENYL]METHYLENE)-1,3-DIMETHYL-2,4,6(1H,3H,5H)-PYRIMIDINETRIONE(159470-37-8)
• EPA Substance Registry System: 5-([2-(ALLYLOXY)PHENYL]METHYLENE)-1,3-DIMETHYL-2,4,6(1H,3H,5H)-PYRIMIDINETRIONE(159470-37-8)

Safety Data

• Hazardous Substances Data: 159470-37-8(Hazardous Substances Data)

Upstream product

• 90-02-8 salicylaldehyde 
• 28752-82-1 2-(allyloxy)benzaldehyde 
• 769-42-6 1,3-dimethylbarbituric acid 

Relevant articles and documents

Stereoselective intramolecular hetero Diels-Alder reactions of 1-oxa-1,3-butadienes: A novel approach for the synthesis of complex annulated uracils

The intramolecular hetero Diels-Alder reactions of 1-oxa-1,3-butadienes 4, obtained from salicylaldehyde 1 via O-allylation followed by Knoevenagel condensation with barbituric acids 3 in the presence of hydrochloric acid as catalyst, affords the tetracyclic uracil derivatives 5 and 6 in a stereoselective manner and high overall yields.

Inter- and Intramolecular Hetero Diels-Alder Reactions, 49. Kinetics and Selectivity of the Intramolecular Hetero Diels-Alder Reaction of 1-Oxa-1,3-butadienes using a Benzylidenebarbituric Acid Derivative. Effect of Pressure, Temperature, and Solvent

The intramolecular hetero Diels-Alder reaction of the benzylidenebarbituric acid derivative 1 to give the ortho and meta products 2 and 3 is studied under high pressure up to 6 kbar in various solvents.The kinetics is measured by on-line FT-IR spectroscop