159496-17-0Relevant articles and documents
NMR Spectroscopic Determination of the Solution Structure of a Branched Nucleic Acid from Residual Dipolar Couplings by Using Isotopically Labeled Nucleotides
Van Buuren, Bernd N. M.,Schleucher, Juergen,Wittmann, Valentin,Griesinger, Christian,Schwalbe, Harald,Wijmenga, Sybren S.
, p. 187 - 192 (2007/10/03)
Only a small set of magnetic-field-induced residual dipolar couplings is required to determine the global structure of branched nucleic acids. This is demonstrated for the example of the Holliday junction (shown schematically) after 13C labelin
A multigram, stereoselective synthesis of D-[13C5]ribose from D-[13C6]glucose and its conversion into [13C5]nucleosides
Agrofoglio, Luigi A.,Jacquinet, Jean-Claude,Lancelot, Gerard
, p. 1411 - 1412 (2007/10/03)
The preparation of 13C-labeled ribonucleosides starting from D-[13D6]glucose in 45% overall yield is described. The key of this short synthetic way is the dehomologation of di-O-isopropylidene hexofuranose 2 with periodic acid and NaBH4 that afforded stereoselectively the labeled ribofuranose derivative 3 in high yield.