15956-91-9Relevant academic research and scientific papers
Acid and Polarity Effects in Benzene Photoreactions with Alkenes and Alkynes
Bryce-Smith, D.,Gilbert, A.,Al-Jalal, N.,Deshpande, R.R.,Grzonka, J.,et al.
, p. 1101 - 1112 (2007/10/02)
The effects of polar solvents and proton donors on various photoreactions of the benzene ring with electron-acceptor alkenes and alkynes are described and discussed in relation to the various electronic excitation mechanisms involved.Proton donors prove valuable as mechanistic probes for polar intermediates in such processes, and can in some systems both initiate and divert reaction pathways. - Key words: Photoreactions, Benzene, Alkenes, Alkynes, Acid Effects
PHOTOFRAGMENTATION OF OXAZOLIDINES. A NEW METHOD FOR THE GENERATION OF AZIRIDINES
Tsuge, Otohiko,Oe, Koji,Kawaguchi, Noriyuki
, p. 1585 - 1588 (2007/10/02)
Irradiation of 4,5-cis-2,3,4,5-tetraaryloxazolidines and 3-aryl-3a,9b-dihydro-acenaphthoxazolidines generates the corresponding aziridine intermediates with elimination of aldehyde formed by fission of the C2-O and C4-C5 bonds in the former and the C2-O and C2-N bonds int the latter, respectively.The intervention of aziridine intermediates was proved by photo-cycloadditions.
