159598-74-0Relevant academic research and scientific papers
Preparation of olefins and acetylenes via reductive elimination with Sml2-HMPA
Ihara, Masataka,Suzuki, Shuichi,Taniguchi, Takahiko,Tokunaga, Yuji,Fukumoto, Keiichiro
, p. 9873 - 9890 (2007/10/02)
Reaction of β-hydroxy or acetoxy sulfones with Sml2 in the presence of HMPA caused effectively reductive elimination to provide olefins. Treatment of enol phosphates, readily synthesized from β-hydroxy sulfones via keto sulfones, under the same conditions efficiently produced mono- and disubstituted acetylenes.
