1596339-82-0Relevant articles and documents
α-diazo β-keto ester as precursor to aromatic C-H insertion and wolff rearrangement with different directing groups
Ma, Biao,Chen, Fang-Lei,Xu, Xing-Yu,Zhang, Yi-Nan,Hu, Li-Hong
, p. 416 - 420 (2014)
A tunable aromatic C-H insertion and a Wolff rearrangement of α-diazo β-keto esters precursor were developed. Different directing groups on nitrogen led with high selectivity to either dihydroquinoline or 2-carbamoylacrylate motifs, which can be transformed to multiple heterocyclic scaffolds.