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• 3731-51-9 2-(Aminomethyl)pyridine 
• 148-53-8 3-methoxy-2-hydroxybenzaldehyde 

Relevant academic research and scientific papers

Pd(II) complexes with ONN pincer ligand: Tailored synthesis, characterization, DFT, and catalytic activity toward the Suzuki-Miyaura reaction

A pincer type ONN tridentate Schiff base ligand, 2-(((pyridin-2-yl)methylimino)methyl)-6-methoxyphenol, (L1) synthesized by the condensation of 4-hydroxy-3-methoxy-benzaldehyde and (pyridin-2-yl)methanamine. The ligand L1 and the new Pd(II) heteroleptic complexes of the composition [Pd(L1)(L2)]Cl, where L2 = benzimidazole, imidazole, benzooxazol or pyridine were synthesized and characterized by a set of chemical, spectrometric and spectroscopic analyses. These complexes were named 1 to 4, respectively. The FT-IR and DFT have suggested that ligand is coordinated with metal through azomethine-N and phenolic-O and arranged in square planar fashion around the metal. Correlation coefficients value between 0.995 - 0.993 shows satisfactory agreement in theoretical and experimental 1H-NMR and 13C-NMR. Benzimidazole anchored complex 1 exhibits an excellent catalytic activity. DFT calculated the energy profile diagram of the Suzuki-Miyaura reaction.

Synthesis, characterization and crystal structure of a mononuclear copper(II) complex derived from 2-methoxy-6-[(pyridin-2-ylmethylimino)methyl] phenol

Blue needle-shaped crystals of bromo{2-methoxy- 6-[(pyridin-2- ylmethylimino)methyl]phenolate}copper( II), [CuBr(C14H 13N2O2)], have been obtained and characterized by elemental analysis, IR spectrum, and single

Linear shaped hetero-metallic [Zn2Ln4] clusters with Schiff base ligand: Synthesis, characterization and magnetic properties

A series of isostructural 3d–4f coordination clusters (CCs) [Zn2Ln4(L1)4(L2)2(OAc)2(N3)2] [Na2(OH2)2(NO3)3.2(N3)

Synthesis, characterization and magnetic studies of dinuclear lanthanide complexes constructed with a Schiff base ligand

A series of seven isostructural homometallic dinuclear lanthanide metal complexes having the general formula [Ln2(L)2(NO3)4]·2CH3 OH, where L = 6-methoxy-2-(2-pyridylmethyliminomethyl) phenol Ln = Tb

Synthesis, characterization and biological study of Cu(II) complexes of aminopyridine and (aminomethyl)pyridine Schiff bases

The synthesis, characterization and antimicrobial activity determination of some aminopyridine- and (aminomethyl)pyridine–salicylaldimine copper(II) complexes were realized. The ligands, L1–L6, were prepared by condensing salicylalde

A new synthetic route towards binuclear 3d-4f complexes, using non-compartmental ligands derived from o-vanillin. Syntheses, crystal structures, magnetic and luminescent properties

Sixteen new 3d-4f binuclear complexes have been obtained using two Schiff-base ligands, Hvalampy and Hvalaepy, derived from the reaction of o-vanillin and 2-aminomethyl-pyridine or 2-(2-aminoethyl)-pyridine, respectively. Hvalaepy ligand: [Zn(valaepy)sub

Synthesis, characterization, and formation constant of hexacoordinate iron(III) complexes

Twelve iron(III) complexes [FeIII(LX)2]ClO4, where (LX)- is the deprotonated form of a series of asymmetric ligands containing pyridine and substituted phenol moieties (XPh(OH)-CH=N-(CH2)n-Py that X = H, 5-Br, 5-NO2, 5-OMe, 4-OMe, 3-OMe, and n = 1, 2), were synthesized and characterized by H NMR, IR, UV-Vis spectroscopy, mass spectrometry, and elemental analysis. Formation constants were measured using UV-Vis spectrophotometric titration at constant ionic strength (0.10 M NaClO4) at 25 (±0.1)°C. The trend of the complex formation of Fe(III) ion with a given tridentate ligand decreases as follows: 5-OMe > 5-H > 5-NO2 > 5-Br 5-OMe > 4-OMe > 5-OMe.

SPECTROSCOPIC AND SPECTROMAGNETIC PROPERTIES OF COBALT(II) BIS DERIVATIVES WITH TRIDENTATE SCHIFF BASES AND THEIR ADDUCTS WITH MOLECULAR OXYGEN

Schiff bases obtained by condensation of 2-(aminomethyl)pyridine with salicylaldehyde, o-hydroxypropiophenone and 3-methoxysalicylaldehyde were found to act as tridentate ligands, giving high-spin cobalt(II) complexes.Magnetic measurements and electronic