1597407-24-3

Basic information

• Product Name: C₂₇H₂₆ClN₃O₄RuS
• CAS NO: 1597407-24-3
• Molecular Weight: 625.11
• Mol File: 1597407-24-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₇H₂₆ClN₃O₄RuS(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₇H₂₆ClN₃O₄RuS(1597407-24-3)
• EPA Substance Registry System: C₂₇H₂₆ClN₃O₄RuS(1597407-24-3)

Safety Data

• Hazardous Substances Data: 1597407-24-3(Hazardous Substances Data)

Upstream product

• 73901-01-6 p-nitrobenzenesulfonyl azide 
• 811436-73-4 (rac)-chloro(η6-p-cumene)(2-phenylpyridine-κC,N)ruthenium(II) 

Relevant articles and documents

Ruthenium-catalyzed direct C-H amidation of arenes: A mechanistic study

We report mechanistic studies of C-H activitation/amidation reactions using azides as the amino source catalyzed by [RuCl2(p-cymene)] 2. We have achieved two intermediates in the catalytic cycle (C 5H4NC6H4)Ru(p-cymene)Cl and (C 5H4NC6H4)NArRu(p-cymene)Cl (Ar = NO2C6H4SO2). Furthermore, the process from (C5H4NC6H4)Ru(p-cymene) Cl to (C5H4NC6H4)NArRu(p-cymene)Cl was monitored by 19F NMR and a ruthenium-imido species was proposed to explain the formation of the azacyclopropane analogue.