1597444-14-8

Basic information

• Product Name: 9-(2,4,6-trimethoxyphenyl)-9H-fluorene
• Synonyms: 9-(2,4,6-trimethoxyphenyl)-9H-fluorene
• CAS NO: 1597444-14-8
• Molecular Weight: 332.399
• Mol File: 1597444-14-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 9-(2,4,6-trimethoxyphenyl)-9H-fluorene(CAS DataBase Reference)
• NIST Chemistry Reference: 9-(2,4,6-trimethoxyphenyl)-9H-fluorene(1597444-14-8)
• EPA Substance Registry System: 9-(2,4,6-trimethoxyphenyl)-9H-fluorene(1597444-14-8)

Safety Data

• Hazardous Substances Data: 1597444-14-8(Hazardous Substances Data)

Upstream product

• 621-23-8 1,2,3-trimethoxybenzene 
• 86-73-7 9H-fluorene 
• 1203-68-5 2-Phenylbenzaldehyde 

Relevant articles and documents

Cross-Dehydrogenative-Coupling of Alkoxybenzenes with Toluenes: Copper(II) Halide Mediated Tandem Halo/Benzylation of Arenes

A cross-dehydrogenative-coupling of alkoxybenzenes and toluenes with concomitant halogenation is reported. Conditions employed were the use of stoichiometric copper halide salts and dialkylperoxides to afford a range of bromoalkoxydi- and triarylmethanes. Preliminary mechanistic studies suggest that the in situ production of haloarenes (or dihaloarenes) followed by a copper-mediated coupling of a benzylic radical is operational.

TfOH catalyzed synthesis of 9-arylfluorenes via tandem reaction under warm and efficient conditions

A tandem ring-closing reaction was developed for the synthesis of 9-arylfluorenes and their derivatives. The reaction is metal-free, straightforward and efficient under warm conditions. More than 99% yield is obtained. This journal is the Partner Organisations 2014.